ORIGIN OF THE FINE-STRUCTURE IN THE VIBRATIONAL-SPECTRUM OF [PT(C2H8N2)2][PT(C2H8N2)2CL2](CLO4)4 - VIBRATIONAL LOCALIZATION IN A QUASI-ONE-DIMENSIONAL SYSTEM

被引：23

作者：

LOVE, SP

WORL, LA

DONOHOE, RJ

HUCKETT, SC

SWANSON, BI

机构：

[1] Inorganic and Structural Chemistry Group (INC-4), Los Alamos National Laboratory, Los Alamos

来源：

PHYSICAL REVIEW B | 1992年 / 46卷 / 02期

关键词：

D O I：

10.1103/PhysRevB.46.813

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The complex fine structure in the Raman spectrum of the quasi-one-dimensional solid [Pt(C2H8N2)2][Pt(C2H8N2)2Cl2](ClO4)4 is shown, through studies of isotopically enriched materials and lattice-dynamics calculations, to originate from vibrational modes strongly localized by the positional disorder of the two naturally occurring Cl isotopes, making this an elegant example of a real material displaying vibrational localization in one dimension. The modes responsible for the observed features reside on short chain segments defined by a few statistically favored sequences of isotopes.

引用

页码：813 / 816

页数：4

共 18 条

[1] VIBRATIONAL STUDIES OF, AND MODEL FOR, HALOGEN-BRIDGED LINEAR-CHAIN MIXED-VALENCE COMPLEXES
ALLEN, SD
CLARK, RJH
CROUD, VB
KURMOO, M
[J]. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1985, 314 (1528): : 131 - 144
[2] LOCALIZED POLARONIC STATES IN MIXED-VALENCE LINEAR-CHAIN COMPLEXES
BAERISWYL, D
BISHOP, AR
[J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (02): : 339 - 356
[3] BARKER AS, 1975, REV MOD PHYS S2, V47
[4] PREPARATION AND STRUCTURAL INVESTIGATION OF SOME NEW WOLFFRAMS SALT ANALOGS - [PT(L-L)2] [PT(L-L)2X2] (CLO4)4
BEKAROGLU, O
BREER, H
ENDRES, H
KELLER, HJ
NAMGUNG, H
[J]. INORGANICA CHIMICA ACTA, 1977, 21 (02) : 183 - 186
[5] PHENOMENOLOGICAL DESCRIPTION OF THE LONGITUDINAL VIBRATIONS OF THE QUASI-ONE-DIMENSIONAL SOLID PTCL - CALCULATION OF THE VALENCE DEFECT FREQUENCIES
BULOU, A
DONOHOE, RJ
SWANSON, BI
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1991, 3 (12) : 1709 - 1726
[6] RESONANCE RAMAN-SPECTRA OF METAL-II/IV DIMER CHAIN COMPLEXES OF PLATINUM AND PALLADIUM - ANALYSIS OF THE COMPONENT STRUCTURE TO THE BAND ASSIGNED TO THE SYMMETRIC XMX CHAIN STRETCHING MODE (X=CL OR BR)
CLARK, RJH
MICHAEL, DJ
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1988, 189 (1-2) : 173 - 185
[7] EXCITATION WAVENUMBER DEPENDENCE OF THE SYMMETRIC CHAIN-STRETCHING MODE OF LINEAR-CHAIN MIXED-VALENCE PLATINUM COMPLEXES
CLARK, RJH
KURMOO, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1983, 79 : 519 - 527
[8] CHARGE-DENSITY WAVES AND LOCAL STATES IN QUASI-ONE-DIMENSIONAL MIXED-VALENCE INORGANIC COMPLEXES
CONRADSON, SD
STROUD, MA
ZIETLOW, MH
SWANSON, BI
BAERISWYL, D
BISHOP, AR
[J]. SOLID STATE COMMUNICATIONS, 1988, 65 (07) : 723 - 729
[9] VIBRATIONAL SPECTRA OF DIATOMIC CHAINS
DEAN, P
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 254 (1279): : 507 - 521
[10] VIBRATIONAL SPECTRA OF DIATOMIC CHAINS .2.
DEAN, P
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1961, 260 (1300) : 263 - +

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