The absorption spectrum and photoluminescence spectrum of multiwalled carbon nanotubes(MWNTs) and the peaks related with Van Hove singularities(VHS) were obtained experimentally. Both the VHS formation and the change of band gaps in MWNTs depend on the intershell interaction. The VHS makes the probability of optical transitions enhanced, but the intershell interaction suppresses such radiative transitions. The excitation in the experiment involves a two-photon absorption process and the emission light has the effect of the optical frequency up-conversion.
机构:
Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R ChinaUniv Wollongong, ISEM, AIIM, Wollongong, NSW 2525, Australia
Chen, Lan
Ni, Zhenyi
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Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R ChinaUniv Wollongong, ISEM, AIIM, Wollongong, NSW 2525, Australia
Ni, Zhenyi
Liu, Chen
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Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R ChinaUniv Wollongong, ISEM, AIIM, Wollongong, NSW 2525, Australia
机构:
Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R ChinaUniv Wollongong, ISEM, AIIM, Wollongong, NSW 2525, Australia
Wang, Jiaou
Pi, Xiaodong
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Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R ChinaUniv Wollongong, ISEM, AIIM, Wollongong, NSW 2525, Australia