THE STRUCTURE OF ISOSTRYCHNOPENTAMINE, A BISINDOLE MONOTERPENE ALKALOID FROM STRYCHNOS-USAMBARENSIS

被引：12

作者：

TAVERNIER, D

ZHANG, W

ANGENOT, L

CHIERICITITS, M

LECLERCQ, J

机构：

[1] UNIV LIEGE, PHARMACOGNOSIE LAB, RUE FUSCH 5, B-4000 LIEGE, BELGIUM

[2] STATE UNIV GHENT, ORGAN CHEM LAB, B-9000 GHENT, BELGIUM

来源：

PHYTOCHEMISTRY | 1987年 / 26卷 / 02期

关键词：

D O I：

10.1016/S0031-9422(00)81453-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The alkaloid isotrychnopentamine has been shown to be epimeric with strychnopentamine at the asymmetric carbon atom at the N-methylpyrrolidin-2-yl group. Its IUPAC name is 2-[-(1'',2'',3'',4''-tetrahydro-2''-methyl-.beta.-carbolin-1''-yl)methyl]-11-(1"-methyl-pyrrolidine-2"-yl)-3-vinyl-1,2,3,4,6,7,12,12b-octahydro-indolo[2,3-a]quinolizin-10-ol [2(S),3(R),12b(S),1''(S),2"(S)].

引用

页码：557 / 560

页数：4

共 8 条

[1]

Angenot L, 1978, J Pharm Belg, V33, P11

[2]

BAX A, 1982, 2 DIMENSIONAL NUCLEA

[3]

CRABB TA, 1982, ANNU REP NMR SPECTRO, V13, P59

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF NEW BISINDOLIC ALKALOID - STRYCHNOPENTAMINE [J].

DUPONT, L ;

LAMOTTEBRASSEUR, J ;

DIDEBERG, O ;

CAMPSTEYN, H ;

VERMEIRE, M ;

ANGENOT, L .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JUN15) :1801-1807

[5] SOLUTION CONFORMATION OF NICOTINE - H-1 AND H-2 NUCLEAR MAGNETIC-RESONANCE INVESTIGATION [J].

PITNER, TP ;

EDWARDS, WB ;

BASSFIELD, RL ;

WHIDBY, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (01) :246-251

[6]

Shamma M., 1979, CARBON 13 NMR SHIFT

[7] ANTIMITOTIC ACTIVITY OF STRYCHNOPENTAMINE, A BISINDOLIC ALKALOID [J].

TITS, M ;

DESAIVE, C ;

MARNETTE, JM ;

BASSLEER, R ;

ANGENOT, L .

JOURNAL OF ETHNOPHARMACOLOGY, 1984, 12 (03) :287-292

[8]

ZECHES M, 1981, B SOC CHIM FR II-CH, P75

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