AN UNEXPECTED ACYLOIN REARRANGEMENT AND OXIDATION OF A CAMPHOR DERIVATIVE

被引：7

作者：

MCINTOSH, JM ^{[1
]}

CASSIDY, KC ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1991年 / 69卷 / 08期

关键词：

CAMPHOR; ACYLOIN REARRANGEMENT;

D O I：

10.1139/v91-195

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trimethylsiyl ether 7 derived in two steps from camphor underwent ring expansion via an acylion rearrangement to afford two products (8 and 9) when desilylation was attempted. Compound 9 was stable but 8 was oxidized in air to homocamphoric acid anhydride 11.

引用

页码：1315 / 1319

页数：5

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