ENANTIOSELECTIVE HYDROBORATIONS CATALYZED BY RHODIUM(+1) COMPLEXES

被引：59

作者：

BURGESS, K

VANDERDONK, WA

OHLMEYER, MJ

机构：

[1] Chemistry, Rice University, Houston, TX 77251

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86113-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-MeODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+1)/DIOP catalysts. Trends in the observed optical purities are discussed.

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页码：613 / 621

页数：9

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