INFRARED SPECTROSCOPIC STUDIES OF THE HYDROLYSIS REACTION DURING LEACHING OF HEAVY-METAL FLUORIDE GLASSES

被引：0
作者：
LETOULLEC, M
SIMMONS, CJ
SIMMONS, JH
机构：
[1] Univ of Florida, Gainesville, FL,, USA, Univ of Florida, Gainesville, FL, USA
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1988年 / 71卷 / 04期
关键词：
MATERIALS SCIENCE - SPECTROSCOPY; INFRARED; -; WAVEGUIDES; OPTICAL; Materials;
D O I：
暂无
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The interfacial reactions of heavy-metal fluoride glasses with water have been investigated by Fourier transform infrared spectroscopy. High dilution and stirring conditions were maintained to prevent any influence of pH drift and reprecipitation. From comparisons of the integrated absorption peak areas for the O-H stretching and H-O-H bending vibrations in the glass with those for molecular water, the contributions of metal hydroxyls formed in the corrosion layer can be separated from the total O-H band.
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页码：219 / 224
页数：6
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