QUASI-RELATIVISTIC EFFECTS IN THE ELECTRONIC-STRUCTURE OF THE THIOMOLYBDATE AND THIOTUNGSTATE COMPLEXES OF NICKEL, PALLADIUM, AND PLATINUM

被引：6

作者：

ELISSA, BD ^{[1
]}

ZEEDAN, MM ^{[1
]}

机构：

[1] KUWAIT UNIV,DEPT CHEM,SAFAT 13060,KUWAIT

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 12期

关键词：

D O I：

10.1021/ic00012a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, we present a comparative study of the thiomolybdate and the thiotungstate complexes of the formula [M'(MS4)2]2- (M' = Ni, Pd, Pt; M = Mo, W). The electronic structure and the bonding properties of these complexes are discussed by using the quasirelativistic multiple scattering X-alpha method. We have repeated the calculations for the [Pt(WS4)2]2- complex ion without incorporating the mass velocity and the Darwin corrections around the Pt sphere, and certain conclusions are obtained regarding the relativistic and the nonrelativistic effects on these complex ions. Transition and ionization energies are also discussed.

引用

页码：2594 / 2605

页数：12

共 59 条

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