P-31 NMR-STUDY OF THE SOLID-SOLUTION SYSTEM LI1+XT2-XINXP3O12

被引：2

作者：

YUE, Y ^{[1
]}

DENG, F ^{[1
]}

HU, HB ^{[1
]}

YE, CH ^{[1
]}

LIN, ZX ^{[1
]}

TIAN, SB ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST CERAM,SHANGHAI 200050,PEOPLES R CHINA

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 208卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(93)89081-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of the Li1-xTi2-xInxP3O12 solid solution system was investigated by means of the P-31 MAS NMR technique. The results indicate that In 3+ ions can substitute for Ti4+ ions in the lattice of LiTi2P3O12 and a series of homogeneous solid solutions without amorphous and other phosphate phases is formed. The five basic structure units Q0(4-yTi, yIn) (y = 1, 2, 3, 4) of the compound are predicated from the resulting P-31 NMR spectra. The resonant frequencies for those structures can be determined by a linear correlation between the P-31 isotropic chemical shift and the field strength of the cations.

引用

页码：311 / 314

页数：4

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