SEEDED EMULSION POLYMERIZATION OF BUTYL ACRYLATE

被引:5
作者
CAPEK, I
机构
关键词
D O I
10.1002/actp.1991.010420608
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The emulsion polymerization of butyl acrylate initiated by ammonium peroxodisulfate in the presence of poly(ethyl acrylate) seed particles was kinetically investigated. The dependence of the final particle number on the initiator concentration deviates from the predictions of emulsion polymerization. The rate of polymerization decreases with increasing monomer concentration. The polymerization behaviour was explained by the polymerization in both the monomer-swollen emulsifier micelles and the monomer-swollen polymer particles.
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页码:273 / 277
页数:5
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