SOLUTE SOLUTE CORRELATIONS IN INFINITELY DILUTE SUPERCRITICAL MIXTURES

被引：26

作者：

DEBENEDETTI, PG

CHIALVO, AA

机构：

[1] Department of Chemical Engineering, Princeton University, Princeton

[2] Department of Chemical Engineering, University of Virginia, Charlottesville

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 01期

关键词：

D O I：

10.1063/1.463596

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymptotic expressions for the solute-solute pair correlation integral and for the limiting slope of the composition dependence of the solute's activity coefficient are derived for the situation in which the solvent's critical point is approached while the mixture is kept at infinite dilution. Both quantities diverge to plus infinity and scale as the solvent's compressibility, with prefactors that depend on the temperature, solvent density, and the infinite dilution limit of the solute-solvent direct correlation function integral.

引用

页码：504 / 507

页数：4

共 37 条

[1] NAPHTHALENE TRIETHYLAMINE EXCIPLEX AND PYRENE EXCIMER FORMATION IN SUPERCRITICAL FLUID SOLUTIONS [J].