ANODIC ELECTROPOLYMERIZATION OF FILMS OF POLYPYRROLE FUNCTIONALIZED WITH METAL TERPYRIDYL REDOX CENTERS

被引：39
作者：
COLLIN, JP
JOUAITI, A
SAUVAGE, JP
机构：
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 286卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(90)85065-D
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Several complexes of the type ML2+2 (M= Mn, Fe, Ru, Ni, Co), MLCl3 (M = Rh, Ru) and ML(bp) (OH2)2+ (M = Ru, bp = 2,2'-bipyridine) with L = 4'-(para-pyrrolylmethyl-phenyl)-2,2':6',2″-terpyridine have been prepared and characterized. Their anodic electropolymerization and electrochemical behaviour are described. Electron transfer to solution species may occur either via diffusion through the polymer matrix or via redox conduction through the film. Attempts to electro-oxidize various substrates were carried out. Positive results were obtained when the system behaves as an electron mediator. © 1990.
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页码：75 / 87
页数：13
相关论文
共 46 条
[1]   RECTIFYING INTERFACES USING 2-LAYER FILMS OF ELECTROCHEMICALLY POLYMERIZED VINYLPYRIDINE AND VINYLBIPYRIDINE COMPLEXES OF RUTHENIUM AND IRON ON ELECTRODES [J].
ABRUNA, HD ;
DENISEVICH, P ;
UMANA, M ;
MEYER, TJ ;
MURRAY, RW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :1-5
[2]  
ANDRIEUX CP, 1986, J AM CHEM SOC, V108, P815
[3]  
BENHADDA T, 1988, POLYHEDRON, V7, P575
[4]   EVALUATION OF ROLE OF FAR INFRARED SPECTROSCOPY IN STUDY OF RHODIUM(III) HALIDE COMPLEXES WITH NITROGEN HETEROCYCLIC LIGANDS [J].
BHAYAT, II ;
MCWHINNI.WR .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1972, A 28 (04) :743-&
[5]  
BIDAN G, 1984, NOUV J CHIM, V8, P501
[6]   ELECTROACTIVE FILMS OF [CU(2,9-DIPHENYL-1,10-PHENANTHROLINE)2]+ COVALENTLY ATTACHED TO POLYPYRROLE [J].
BIDAN, G ;
DIVISIABLOHORN, B ;
KERN, JM ;
SAUVAGE, JP .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) :723-724
[7]   CYCLIC AND DIFFERENTIAL PULSE VOLTAMMETRIC BEHAVIOR OF REACTANTS CONFINED TO ELECTRODE SURFACE [J].
BROWN, AP ;
ANSON, FC .
ANALYTICAL CHEMISTRY, 1977, 49 (11) :1589-1595
[8]   ELECTROCATALYSIS OF CO2 REDUCTION AT SURFACE MODIFIED METALLIC AND SEMICONDUCTING ELECTRODES [J].
CABRERA, CR ;
ABRUNA, HD .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 209 (01) :101-107
[9]   SPECTRAL, ELECTROCHEMICAL, AND CONDUCTIVITY STUDIES OF POLY(PYRIDYL)RUTHENIUM COMPLEXES CONTAINING POLYMERIZABLE ACETYLENIC AND OLEFINIC LIGANDS [J].
CALVERT, JM ;
PEEBLES, DL ;
NOWAK, RJ .
INORGANIC CHEMISTRY, 1985, 24 (20) :3111-3119
[10]   POLY(PYRIDYL)RUTHENIUM(II) COMPLEXES OF POLY(4-VINYLPYRIDINE) - SYNTHESIS, CHARACTERIZATION, AND INVESTIGATION OF OPTICAL AND ELECTROCHEMICAL PROPERTIES [J].
CALVERT, JM ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1981, 20 (01) :27-33
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