Dichlorido(6-methyl-2,2'-bipyridine-kappa(2) N, N') cobalt(II)

被引：2

作者：

Torbati, Niloufar Akbarzadeh ^{[1
]}

Rezvani, Ali Reza ^{[1
]}

Saravani, Hamideh ^{[1
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, POB 98135-674, Zahedan, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 22.8; mean ̄(C-C) = 0.007 Å; R factor = 0.058; single-crystal X-ray study; T = 298 K; wR factor = 0.131;

D O I：

10.1107/S1600536812041116

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [CoCl2(C11H10N2)], the Co II atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Intermolecular C-H center dot center dot center dot Cl hydrogen bonds and pi-pi stacking interactions between the pyridine rings [centroidcentroid distance = 3.745 (3) angstrom] are present in the crystal.

引用

页码：M1332 / +

页数：7

共 17 条

[1] Dichlorido(6-methyl-2,2′-bipyridine k2N,N′)zinc(II) [J].

Ahmadi, Roya ;

Kalateh, Khadijeh ;

Ebadi, Amin ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1266-U473

[2] Tetrakis(6-methyl-2,2′-bipyridine)-1κ2N,N′;2κ2N,N′;3κ2N,N′;4κ2N,N′-tetra-μ-nitrato-1:2κ2O:O′;2:3κ3O:O′,O";2:3κ3O,O′:O";3:4κ2O:O′-tetranitrato-1κ4O,O′;4κ2O,O′-tetralead(II) [J].

Ahmadi, Roya ;

Kalateh, Khadijeh ;

Alizadeh, Robabeh ;

Khoshtarkib, Zeinab ;

Amani, Vahid .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1169-+

[3] Dichlorido(6-methyl-2,2′-bipyridine-κ2N,N′)mercury(II) [J].

Ahmadi, Roya ;

Ebadi, Amin ;

Kalateh, Khadijeh ;

Norouzi, Ali ;

Amani, Vahid .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1407-U551

[4] Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza ;

Akkurt, Mehmet .

POLYHEDRON, 2009, 28 (14) :3026-3030

[5]

Bruker, 2001, SADABS

[6]

Bruker, 2007, APEX2 SAINT

[7]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]

[8] Dibromido(6-methyl-2,2′-bipyridine-κ2N,N′)zinc(II) [J].

Kalateh, Khadijeh ;

Ahmadi, Roya ;

Amani, Vahid .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M1241-U670

[9]

Macrae CF, 2006, J APPL CRYSTALLOGR, V39, P453, DOI 10.1107/S0021 88980600731X

[10] CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .78. ACUTE BONDING DEVIATION IN SQUARE-PLANAR D8 PALLADIUM(II) COMPLEXES [J].

NEWKOME, GR ;

FRONCZEK, FR ;

GUPTA, VK ;

PUCKETT, WE ;

PANTALEO, DC ;

KIEFER, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (06) :1782-1783

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