Chlorido{[(E)-2-(diphenylphosphanyl)benzylidene](furan-2-ylmethyl)amine-kappa P}gold(I)

被引：0

作者：

Chiririwa, Haleden ^{[1
]}

Davis, Wade L. ^{[2
]}

机构：

[1] Univ Cape Town, Dept Chem, Private Bag, ZA-7707 Rondebosch, South Africa

[2] Univ Johannesburg, Res Ctr Synth & Catalysis, Dept Chem, ZA-2006 Johannesburg, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536812050404

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au-I atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321 (13) angstrom, Au-Cl = 2.2820 (13) angstrom and P-Au-Cl = 176.49 (5)degrees. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio.

引用

页码：M53 / +

页数：8

共 12 条

[1]

Barnard P. J., 2004, J INORG BIOCHEM, V98, P115

[2]

Brandenburg K., 2005, DIAMOND CRYSTAL IMPA

[3]

Bruker, 2007, APEX2 SADABS SAINT X

[4] Synthesis, characterisation and in vitro evaluation of platinum(II) and gold(I) iminophosphine complexes for anticancer activity [J].

Chiririwa, Haleden ;

Moss, John R. ;

Hendricks, Denver ;

Smith, Gregory S. ;

Meijboom, Reinout .

POLYHEDRON, 2013, 49 (01) :29-35

[5] Chlorido{N-[(E)-2-(diphenylphosphanyl)benzylidene]-2-(thiophen-2-yl)ethanamine-κP}gold(I) [J].

Chiririwa, Haleden ;

Muller, Alfred .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 :M49-+

[6] WinGX and ORTEP for Windows: an update [J].

Farrugia, Louis J. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854

[7] Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and catalytic oligomerisation of ethylene [J].

Mogorosi, Mokgolela M. ;

Mahamo, Tebello ;

Moss, John R. ;

Mapolie, Selwyn F. ;

Slootweg, J. Chris ;

Lammertsma, Koop ;

Smith, Gregory S. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (23) :3585-3592

[8] Ligand-exchangeability of 2-coordinate phosphinegold(I) complexes with AuSP and AuNP cores showing selective antimicrobial activities against Gram-positive bacteria.: Crystal structures of [Au(2-Hmpa)(PPh3)] and [Au(6-Hmna)(PPh3)] (2-H2mpa=2-mercaptopropionic acid, 6-H2mna=6-mercaptonicotinic acid) [J].

Nomiya, K ;

Yamamoto, S ;

Noguchi, R ;

Yokoyama, H ;

Kasuga, NC ;

Ohyama, K ;

Kato, C .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 95 (2-3) :208-220

[9] Gold-based therapeutic agents [J].

Shaw, CF .

CHEMICAL REVIEWS, 1999, 99 (09) :2589-2600

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

← 1 2 →