NEW FERROELECTRIC LIQUID-CRYSTALLINE POLYSILOXANES CONTAINING CYANOHYDRIN CHIRAL MESOGENS - L-NORLEUCINE SERIES

被引:16
作者
SHENOUDA, IG
CHIEN, LC
机构
[1] KENT STATE UNIV,INST LIQUID CRYSTAL,KENT,OH 44242
[2] KENT STATE UNIV,CTR NSF ALCOM,KENT,OH 44242
关键词
D O I
10.1021/ma00071a006
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis and mesomorphic properties of three liquid-crystalline side-chain polymers with a cyanohydrin chiral center are described. The optically active cyanohydrin moiety was synthesized from the naturally occurring optically active amino acid L-Norleucine. The polysiloxanes were prepared by the hydrosilation of cyanohydrin monomers with poly(hydromethylsiloxane). All the polymers exhibit a wide range of the chiral smectic C phase (S(c)*).
引用
收藏
页码:5020 / 5023
页数:4
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