(MU-ALKOXO)DIIRON(II,II) COMPLEXES OF N,N,N',N'-TETRAKIS(2-(6-METHYLPYRIDYL)METHYL)-1,3-DIAMINOPROPANE-2-OLATE AND THE REVERSIBLE FORMATION OF THE O2-ADDUCTS

被引：43

作者：

HAYASHI, Y

SUZUKI, M

UEHARA, A

MIZUTANI, Y

KITAGAWA, T

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, KANAZAWA, ISHIKAWA 920, JAPAN

[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 01期

关键词：

D O I：

10.1246/cl.1992.91

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(mu-Alkoxo)(mu-carboxylato)diiron(II,II) complexes with hindered dinucleating ligand were synthesized and the structure of mu-benzoato derivative was determined by X-ray analysis. The complexes showed reversible oxygenation in acetonitrile and dichloromethane. Resonance Raman spectra of these species demonstrated a possibility of unsymmetrical mu-eta(1)-eta(1') binding of the oxygen toward the diiron centers.

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页码：91 / 94

页数：4

相关论文

共 9 条

[1] A NEW PYRIDYL-CONTAINING PENTAAZA MACROCYCLIC LIGAND - STABILIZATION IN AQUEOUS-SOLUTIONS OF THE IRON(II) COMPLEX AND ITS DIOXYGEN ADDUCT [J].

KIMURA, E ;

KODAMA, M ;

MACHIDA, R ;

ISHIZU, K .

INORGANIC CHEMISTRY, 1982, 21 (02) :595-602

[2] SYNTHETIC MODEL FOR DIOXYGEN BINDING-SITES OF NONHEME IRON PROTEINS - X-RAY STRUCTURE OF FE(OBZ)(MECN)(HB(3,5-IPR2PZ)3) AND RESONANCE RAMAN EVIDENCE FOR REVERSIBLE FORMATION OF A PEROXO ADDUCT [J].

KITAJIMA, N ;

FUKUI, H ;

MOROOKA, Y ;

MIZUTANI, Y ;

KITAGAWA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6402-6403

[3] OXO-BRIDGED POLYIRON CENTERS IN BIOLOGY AND CHEMISTRY [J].

LIPPARD, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :344-361

[4]

MENAGE S, 1990, J AM CHEM SOC, V112, P6425

[5] THERMODYNAMICS OF OXYGEN BINDING IN NATURAL AND SYNTHETIC DIOXYGEN COMPLEXES [J].

NIEDERHOFFER, EC ;

TIMMONS, JH ;

MARTELL, AE .

CHEMICAL REVIEWS, 1984, 84 (02) :137-203

[6] COPPER(II), COBALT(II), NICKEL(II) AND IRON(III) COMPLEXES OF SOME N,N,N',N'-TETRAKIS[(2-BENZ[D]IMIDAZOLYL)METHYL] ALKANEDIAMINES [J].

SAKURAI, T ;

KAJI, H ;

NAKAHARA, A .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1982, 67 (01) :1-5

[7] DINUCLEAR COBALT(II) COMPLEXES CONTAINING 1,3-(OR 1,5-)BIS[BIS-(2-PYRIDYLMETHYL)AMINO]-2-PROPANOLATO (OR -3-PENTANOLATO) - PREPARATION AND REACTION WITH MOLECULAR-OXYGEN [J].

SUZUKI, M ;

SUGISAWA, T ;

UEHARA, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (04) :1115-1120

[8] DINUCLEAR COBALT(II) COMPLEXES WITH VARIOUS DINUCLEATING LIGANDS AND THEIR DIOXYGEN COMPLEXES [J].

SUZUKI, M ;

KANATOMI, H ;

MURASE, I .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (01) :36-42

[9] MOLECULAR-STRUCTURE OF A BINUCLEAR COBALT DIOXYGEN COMPLEX, [CO2(2,6-BIS[BIS(2-PYRIDYLMETHYL)AMINOMETHYL]-4-METHYLPHENOLATO) (BENZOATO)DIOXYGEN] (BF4)2.2H2O [J].

SUZUKI, M ;

UEDA, I ;

KANATOMI, H ;

MURASE, I .

CHEMISTRY LETTERS, 1983, (02) :185-188