COORDINATIVELY UNSATURATED BINUCLEAR CLUSTERS OF RHODIUM - THE REACTIVITY OF [(PRI2P(CH2)NPPRI2)RH]2(MU-H)2 (N = 2, 3, AND 4) WITH DIHYDROGEN, AND THEIR USE IN THE CATALYTIC-HYDROGENATION OF OLEFINS

被引：48

作者：

FRYZUK, MD ^{[1
]}

PIERS, WE ^{[1
]}

EINSTEIN, FWB ^{[1
]}

JONES, T ^{[1
]}

机构：

[1] SIMON FRASER UNIV, DEPT CHEM, BURNABY V5S 2N2, BC, CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY | 1989年 / 67卷 / 05期

关键词：

D O I：

10.1139/v89-137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：883 / 896

页数：14

共 37 条

[1] 1,1,2,2,2,2,3,3,3,3-DECACARBONYL-1-(ETA-CYCLOHEXA-1,3-DIENE)-TRIANGULO-TRIOSMIUM - NOVEL INTERMEDIATE IN SYNTHETIC OSMIUM CLUSTER CHEMISTRY [J].

BRYAN, EG ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (14) :1328-1330

[2] COORDINATELY UNSATURATED CLUSTERS - A NOVEL CATALYTIC REACTION [J].

BURCH, RR ;

SHUSTERMAN, AJ ;

MUETTERTIES, EL ;

TELLER, RG ;

WILLIAMS, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) :3546-3556

[3] REACTION OF CARBON-MONOXIDE WITH THE COORDINATELY UNSATURATED METAL DIMER (MU-H)2RH2[P(O-IOTA-C3H7)3]4 WITH RETENTION OF DIMERIC FORM - CRYSTAL AND MOLECULAR-STRUCTURE OF RH2(MU-CO)2[P(O-IOTA-C3H7)3]4 [J].

BURCH, RR ;

MUETTERTIES, EL ;

SCHULTZ, AJ ;

GEBERT, EG ;

WILLIAMS, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5517-5522

[4]

DEEMING AJ, 1986, ADV ORGANOMET CHEM, V26, P1

[5]

FRYZUK MD, 1984, J CHEM SOC CHEM COMM, P1556, DOI 10.1039/c39840001556

[6] SYNTHESIS AND CATALYTIC POTENTIAL OF COORDINATIVELY UNSATURATED RHODIUM HYDRIDE CLUSTERS INCORPORATING CHELATING BIDENTATE LIGANDS [J].

FRYZUK, MD .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (06) :1347-1351

[7] SYNTHESIS, STABILITY, AND FLUXIONAL BEHAVIOR OF BINUCLEAR MIXED-HYDRIDE TETRAHYDROBORATE COMPLEXES OF HAFNIUM(IV) - X-RAY CRYSTAL-STRUCTURE OF [[(ME2PCH2SIME2)2N]HF(BH4)2](MU-H)3[HF(BH4)[N(SIME2CH2PME2)2]] [J].

FRYZUK, MD ;

RETTIG, SJ ;

WESTERHAUS, A ;

WILLIAMS, HD .

INORGANIC CHEMISTRY, 1985, 24 (25) :4316-4325

[8] FUNDAMENTAL PROCESSES AT POLYNUCLEAR CENTERS - KINETIC-ANALYSIS OF THE REACTION OF A CARBON-NITROGEN DOUBLE-BOND WITH THE RH-2(ETA-H)2 CORE OF BINUCLEAR RHODIUM HYDRIDES [J].

FRYZUK, MD ;

PIERS, WE .

ORGANOMETALLICS, 1988, 7 (09) :2062-2065

[9] COORDINATIVELY UNSATURATED CLUSTERS OF RHODIUM INCORPORATING CHELATING BIDENTATE LIGANDS - SYNTHESIS OF [(CH3O)2PCH2CH2P(OCH3)2)RHH]4 AND [(I-C3H7O)2PCH2CH2P(O-I-C3H7)2)RHH]2 [J].

FRYZUK, MD .

ORGANOMETALLICS, 1982, 1 (02) :408-409

[10] REACTION OF OLEFINS AND DIENES WITH BINUCLEAR RHODIUM HYDRIDE COMPLEXES TO GENERATE BRIDGING ALKENYL, DIENYL AND DIENE UNITS [J].

FRYZUK, MD ;

PIERS, WE .

POLYHEDRON, 1988, 7 (10-11) :1001-1014

← 1 2 3 4 →