CHEMISTRY OF DIOXIRANES .27. SOLVENT TUNING OF DIASTEREOSELECTIVITY IN DIMETHYLDIOXIRANE EPOXIDATION REACTIONS

被引：51

作者：

MURRAY, RW

SINGH, M

WILLIAMS, BL

MONCRIEFF, HM

机构：

[1] Department of Chemistry, University of Missouri-St. Louis, St. Louis

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 14期

关键词：

D O I：

10.1016/0040-4039(95)00310-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diastereoselectivity in the epoxidation of cyclohex-2-en-1-ol shows a remarkable solvent dependence. In some solvent systems the substrate OH group apparently can provide a cis selectivity through H-bonding.

引用

页码：2437 / 2440

页数：4

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