LOW-WAVE-NUMBER VIBRATIONAL RAMAN OPTICAL-ACTIVITY OF CARBOHYDRATES

被引：28

作者：

BELL, AF ^{[1
]}

HECHT, L ^{[1
]}

BARRON, LD ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1993年 / 24卷 / 09期

关键词：

D O I：

10.1002/jrs.1250240913

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A high optical density holographic notch filter in combination with a single-grating spectrograph was used to increase the spectral range for backscattered Raman optical activity (ROA) measurements of biological molecules in aqueous solution towards lower wavenumber. ROA spectra Of D-galaCtose, D-maltose and laminarin starting at ca. 350 cm-1 are presented as first examples. An ROA couplet observed at 427 +/- 10 cm-1 in the spectra of D-maltose, D-cellobiose and laminarin appears to reflect the configuration of glycosidic links in di- and polysaccharides.

引用

页码：633 / 635

页数：3

共 20 条

[1]

BARRON LD, 1993, ADV SPECTROSC, V21, P235

[2]

BARRON LD, 1982, MOL LIGHT SCATTERING

[3]

BARRON LD, 1990, TETRAHEDRON-ASYMMETR, V8, P513

[4]

BELL AF, UNPUB CARBOHYDR RES