EFFECTS OF REPEAT UNIT STRUCTURE ON THE TOUGHNESS OF POLY(ARYL ETHER SULPHONE)S

被引:4
作者
ATTWOOD, TE [1 ]
CINDEREY, MB [1 ]
ROSE, JB [1 ]
机构
[1] ICI PLC,DIV PLAST,WELWYN GARDEN CIT AL7 1HD,HERTS,ENGLAND
关键词
TOUGHNESS; POLY(ARYL ETHER SULPHONE)S; REPEAT UNIT STRUCTURE;
D O I
10.1016/0032-3861(93)90794-B
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Notched impact strength (NIS) has been determined (before and after thermal ageing at 150-degrees-C) as a measure of toughness for a wide range of poly(aryl ether sulphone)s and the results correlated with the structure of the polymers' repeat units. It appears that the most important structural factor determining toughness is the symmetry of the extended polymer chains; the incorporation of repeat units that disrupt symmetry leads to large reductions in NIS, while the introduction of structures that increase symmetry provides a significant improvement.
引用
收藏
页码:1322 / 1324
页数:3
相关论文
共 17 条
[1]  
Attwood T. E., 1977, POLYMER, V18, P369, DOI [10.1016/0032-3861(77)90085-4, DOI 10.1016/0032-3861(77)90085-4]
[2]   SYNTHESIS AND PROPERTIES OF POLYARYLETHERKETONES [J].
ATTWOOD, TE ;
DAWSON, PC ;
FREEMAN, JL ;
HOY, LRJ ;
ROSE, JB ;
STANILAND, PA .
POLYMER, 1981, 22 (08) :1096-1103
[3]   POLY(ARYLENE ETHER SULFONES) BY POLYETHERIFICATION .2. POLYCONDENSATIONS [J].
ATTWOOD, TE ;
BARR, DA ;
KING, T ;
NEWTON, AB ;
ROSE, JB .
POLYMER, 1977, 18 (04) :359-364
[4]  
BRYDSON JA, 1982, PLASTIC MATERIALS, P174
[5]  
CINDEREY MB, 1983, Patent No. 29633
[6]  
CLAYTON HM, 1968, PLASTICS, V33, P76
[7]   EFFECT OF MOLECULAR ENTANGLEMENTS ON CRAZE MICROSTRUCTURE IN GLASSY-POLYMERS [J].
DONALD, AM ;
KRAMER, EJ .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1982, 20 (05) :899-909
[8]  
GOLDEN JH, 1967, J APPL POLYM SCI, V2, P1571
[9]  
ILLERS KH, 1969, MAKROMOL CHEM, V127, P2969
[10]  
KINLOCH AJ, 1983, FRACTURE BEHAV POLYM, P147