C-13-NMR OF MICELLAR SOLUTIONS - MICELLAR AGGREGATION NUMBER FROM THE CONCENTRATION-DEPENDENCE OF THE C-13 CHEMICAL-SHIFTS

被引：118

作者：

PERSSON, BO ^{[1
]}

DRAKENBERG, T ^{[1
]}

LINDMAN, B ^{[1
]}

机构：

[1] UNIV LUND,CTR CHEM,DIV PHYS CHEM,S-22007 LUND 7,SWEDEN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 23期

关键词：

D O I：

10.1021/j100486a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

13C NMR chemical shifts were determined as a function of concentration for aqueous solutions of sodium hexanoate, sodium octanoate, and nonylammonium bromide. Using the mass action law model for micelle formation, we have estimated the aggregation numbers by fitting calculated chemical shifts as a function of amphiphile concentration to the experimental values. For sodium octanoate and sodium hexanoate the calculations indicate the formation of an appreciable amount of premicellar aggregates with an aggregation number of about 3 or 4. For nonylammonium bromide the results are explained by the formation of large aggregates only. © 1979 American Chemical Society.

引用

页码：3011 / 3015

页数：5

共 28 条

[11] THEORY OF SELF-ASSEMBLY OF HYDROCARBON AMPHIPHILES INTO MICELLES AND BILAYERS [J].

ISRAELACHVILI, JN ;

MITCHELL, DJ ;

NINHAM, BW .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1976, 72 :1525-1568

[12]

JONSSON B, CHEM SCRIPT

[13]

KHETRAPAL CL, 1975, LYOTROPIC LIQUID CRY

[14]

Lindman B., 1976, CHLORINE BROMINE IOD

[15]

LINDMAN B, 1977, MICELLIZATION SOLUBI, V1, P195

[16]

LINDMAN B, TOPICS CURRENT CHEM

[17] POLYELECTROLYTES [J].

MANNING, GS .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1972, 23 :117-&

[18] SIZE DISTRIBUTION OF SMALL AND LARGE MICELLES - MULTIPLE EQUILIBRIUM ANALYSIS [J].

MUKERJEE, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (04) :565-&

[19]

Mukerjee P, 1977, MICELLIZATION SOLUBI, V1, P171

[20]

NAKAGAWA T, 1976, SURF COLLOID SCI, V9, P69

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