CIRCULAR-DICHROISM OF A CHIRAL CYANINE DYE DIMER TRAPPED IN GAMMA-CYCLODEXTRIN

被引：33
作者：
BUSS, V
机构：
[1] Fachgebiet Theoretische Chemie, Universität Duisburg, W-4000
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 07期
关键词：
D O I：
10.1002/anie.199108691
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A description as twisted sandwich fits the dimer of the cyanine dye 1, when two gamma-cyclodextrin molecules occupy the central hollow (see sketch on the right). The torque is caused by the chiral interaction between host and guest, which is synergetically magnified by a preferential head-to-head binding of the two halves of the host.
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页码：869 / 870
页数：2
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