TRINUCLEAR COBALT(III) COMPLEXES CONTAINING PARTIAL CUBANE CO3O4 CORE - SYNTHESIS AND STRUCTURE OF [CO-3(L)(3)(MU-OH)(3)(MU(3)-O)]CL (L=ETHYLENEDIAMINE-N-ACETATE)

被引：13

作者：

AMA, T ^{[1
]}

MIYAZAKI, J ^{[1
]}

HAMADA, K ^{[1
]}

OKAMOTO, K ^{[1
]}

YONEMURA, T ^{[1
]}

KAWAGUCHI, H ^{[1
]}

YASUI, T ^{[1
]}

机构：

[1] UNIV TSUKUBA, DEPT CHEM, TSUKUBA, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 04期

关键词：

D O I：

10.1246/cl.1995.267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three isomers of [Co-3(edma)(3)(mu-OH)(3)(mu(3)-O)](+) (edma: ethylenediamine-N-acetate) containing a partial cubane Co3O4 core were prepared and the structure of one of the isomers was determined by the X-ray diffraction method. These isomers are stable at least for 5 days in their neutral aqueous solutions.

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页码：267 / 268

页数：2

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