LIVING RADICAL POLYMERIZATION OF VINYL-ACETATE

被引：132

作者：

MARDARE, D ^{[1
]}

MATYJASZEWSKI, K ^{[1
]}

机构：

[1] CARNEGIE MELLON UNIV,DEPT CHEM,PITTSBURGH,PA 15213

来源：

MACROMOLECULES | 1994年 / 27卷 / 03期

关键词：

D O I：

10.1021/ma00081a003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of well-defined poly(vinyl acetate) in ''living'' radical polymerization is reported. Straight lines in semilogarithmic plots up to >90% conversion indicate internal first order in monomer and a constant concentration of growing species. Molecular weights increase linearly with conversion. The initiating system might,involve persistent radical formed by the ternary complexes of organoaluminum compounds with Lewis bases and stable radicals. This article focuses on the Al(iBu)(3):BPy:TEMPO system. The effect of the composition of the initiating system and its aging is described.

引用

页码：645 / 649

页数：5

共 28 条

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CHERNAYA LI, 1978, ZH OBSHCH KHIM+, V48, P1775

[2]

CHERNAYA LI, 1978, ZH OBSHCH KHIM+, V48, P1780

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