O-QUINONOID COMPOUNDS .I. SYNTHESIS AND TAUTOMERISM OF ISOQUINOLIN-3-OLS

被引：52

作者：

JONES, DW

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 13期

关键词：

D O I：

10.1039/j39690001729

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isoquinolin-3-ol is prepared by reaction of methyl o-formylphenylacetate with liquid ammonia. The 1-methyl, 1-phenyl, and 1,4-diphenyl derivatives are similarly prepared. These compounds exist predominantly as the lactim tautomers in ether solution, whereas in ethanol both tautomeric forms are important. Diels-Alder and photodimerisation reactions of certain isoquinolin-3-ols are described.

引用

页码：1729 / &

共 15 条

[1] ADDITION REACTIONS OF HETEROCYCLIC COMPOUNDS .27. 2-PYRIDONES WITH DIMETHYL ACETYLENEDICARBOXYLATE [J].