NEW TITANIUM BORON COMPLEXES WITH A PLANAR TETRACOORDINATE CARBON OR A PLANAR TRICOORDINATE PHOSPHORUS CENTER

被引：33

作者：

BINGER, P ^{[1
]}

SANDMEYER, F ^{[1
]}

KRUGER, C ^{[1
]}

KUHNIGK, J ^{[1
]}

GODDARD, R ^{[1
]}

ERKER, G ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199401971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coordination geometry of phosphorus is achieved in a simple way by the reaction of the (η2‐tert‐butylphosphaalkyne)titanocene 1 with tetraethyldiborane [Eq. (a)]. The resulting dinuclear complex 2 contains a planar tricoordinate phosphorus atom whose lone pair of electrons is not involved in bonding. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：197 / 198

页数：2

相关论文

共 22 条

[1] SYNTHESIS AND STRUCTURE OF A BRIDGING PHOSPHA-ALKENYL COMPLEX [J].

ARIF, AM ;

COWLEY, AH ;

QUASHIE, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (07) :428-429

[2] ETA-2-TERT-BUTYLPHOSPHAACETYLENE COMPLEXES OF TITANOCENE AND ZIRCONOCENE [J].

BINGER, P ;

BIEDENBACH, B ;

HERRMANN, AT ;

LANGHAUSER, F ;

BETZ, P ;

GODDARD, R ;

KRUGER, C .

CHEMISCHE BERICHTE, 1990, 123 (08) :1617-1623

[3]

Brown H. C., 1962, HYDROBORATION

[4] (ARYNE)METALLOCENE-DERIVED AND (ALKYNE)METALLOCENE-DERIVED DIMETALLIC ZIRCONIUM ALUMINUM COMPLEXES CONTAINING PLANAR-TETRACOORDINATE CARBON [J].

ERKER, G ;

ALBRECHT, M ;

KRUGER, C ;

WERNER, S ;

BINGER, P ;

LANGHAUSER, F .

ORGANOMETALLICS, 1992, 11 (11) :3517-3525

[5]

Erker G, 1992, COMMENTS INORG CHEM, V13, P111, DOI DOI 10.1080/02603599208048461

[6]

ERKER G, 1992, NACHR CHEM TECH LAB, V40, P1099

[7] AN ABINITIO MO STUDY ON STABILIZING INTERACTIONS IN DINUCLEAR ZR/AL COMPLEXES WITH A PLANAR TETRACOORDINATE CARBON CENTER [J].

GLEITER, R ;

HYLAKRYSPIN, I ;

NIU, SQ ;

ERKER, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05) :754-756

[8]

Gleiter R., 1993, ANGEW CHEM, V105, P753

[9] SYNTHESIS OF A PHOSPHAVINYL COMPLEX VIA SHIFT OF A PENTAMETHYLCYCLOPENTADIENYL FROM PHOSPHORUS TO IRON [J].

GUDAT, D ;

NIECKE, E ;

ARIF, AM ;

COWLEY, AH ;

QUASHIE, S .

ORGANOMETALLICS, 1986, 5 (03) :593-595

[10] SYNTHESIS AND CHARACTERIZATION OF LONG-CHAIN ALKYLIDENE-BRIDGED HETERO BIMETALLIC COMPLEXES [J].

HARTNER, FW ;

SCHWARTZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) :4979-4981