EVIDENCE FOR SHORT Cu(I)-Cu(I) DISTANCES IN COPPER-EXCESS SPINELS FROM EXAFS

被引：4
|
作者：
Benazeth, S. [1 ]
Danot, M. [2 ]
Colombet, P. [2 ]
Dexpert, H. [3 ]
Lagarde, P. [3 ]
机构：
[1] Univ Paris 05, Lab Chim Minerale Struct, UA 200, F-75270 Paris 06, France
[2] Univ Nantes, Lab Chim Solides, UA 279, F-44072 Nantes, France
[3] Univ Paris 11, LURE, CNRS UPS, F-91405 Orsay, France
来源：
JOURNAL DE PHYSIQUE | 1986年 / 47卷 / C-8期
关键词：
D O I：
10.1051/jphyscol:19868148
中图分类号：
学科分类号：
摘要：
The Cu2xCr2xSn2-2xS4 spinel compounds have been investigated using EXAFS, especially as far as the structural features of monovalent copper excess are concerned, i.e. for 2x > 1. It has been shown that part of Cu is tetrahedrally surrounded (8a-sites) whereas the remaining part is triangularly coordinated in the vicinity of a face of the usually empty octahedral sites. In addition, the evidence for short Cu-Cu distances (2.35 angstrom) is given, in agreement with the octahedral- and tetrahedral- site arrangement.
引用
收藏
页码：247 / 250
页数：4
相关论文
共 50 条
  • [1] Nanostructures of tetranuclear copper(I) complexes with short Cu(I)•••Cu(I) contacts: crystallization-induced emission enhancement
    Chen, Yong
    Li, Jun-Li
    Tong, Glenna So Ming
    Lu, Wei
    Fu, Wen-Fu
    Lai, Siu-Wai
    Che, Chi-Ming
    CHEMICAL SCIENCE, 2011, 2 (08) : 1509 - 1514
  • [2] Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition
    Ziegler, Micah S.
    Lakshmi, K. V.
    Tilley, T. Don
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) : 5378 - 5386
  • [3] VARIATIONS IN THE CU(I)-CU(I) DISTANCES IN MULTINUCLEAR CLUSTERS WITH IDENTICAL COORDINATION GEOMETRIES - SHORT METAL-METAL CONTACTS INDUCED BY OLIGOMERIZATION
    ABRAHAM, SP
    SAMUELSON, AG
    CHANDRASEKHAR, J
    INORGANIC CHEMISTRY, 1993, 32 (26) : 6107 - 6111
  • [4] Extreme Long and Extreme Short Cu Cu Distances: Nature of Cuprophilicity and Luminescence Modification in Cu(I)-based Cyclic Trinuclear Complexes
    Zheng Ji
    Xing Li-Rui
    Li Dan
    ACTA PHYSICO-CHIMICA SINICA, 2017, 33 (11) : 2133 - 2140
  • [5] HIGHLY DELOCALIZED CU(I)/CU(II) - A COPPER COPPER BOND
    HARDING, C
    MCKEE, V
    NELSON, J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (25) : 9684 - 9685
  • [6] Do Short C-H-M (M = Cu(I), Ag(I)) Distances Represent Agostic Interactions in Pincer-Type Complexes? Unusual NHC Transmetalation from Cu(I) to Ag(I)
    Liu, Xianghao
    Pattacini, Roberto
    Deglmann, Peter
    Braunstein, Pierre
    ORGANOMETALLICS, 2011, 30 (12) : 3302 - 3310
  • [7] DIFFUSION OF CU IN COPPER(I) OXIDE
    TOMLINSON, WJ
    YATES, J
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1977, 38 (10) : 1205 - 1206
  • [8] Cu K-Edge EXAFS characterisation of copper(I) arenethiolate complexes in both the solid and liquid state: Detection of Cu-Cu coordination
    Tromp, M
    van Bokhoven, JA
    Arink, AM
    Bitter, JH
    van Koten, G
    Koningsberger, DC
    CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (24) : 5667 - 5678
  • [9] Mechanochromic photoluminescence in a dinuclear alkynyl copper(<sc>i</sc>) complex with an extremely short Cu(<sc>i</sc>)⋯Cu(<sc>i</sc>) separation
    Moussa, J.
    Julia, F.
    Chamoreau, L. M.
    Gonzalez-Herrero, P.
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (13) : 5577 - 5581
  • [10] Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow-Sphere Structure Featuring Cu2S2 Motifs with Exceptionally Short Cu...Cu Distances
    Frank, Nicolas
    Dallmann, Andre
    Braun-Cula, Beatrice
    Herwig, Christian
    Limberg, Christian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (17) : 6735 - 6739
12345