RATES OF SOLVOLYSIS OF 2-METHYL-2-PROPYL PARA-NITROBENZOATES, 2-TERT-BUTYL-2-PROPYL PARA-NITROBENZOATES, 2-PHENYL-2-PROPYL PARA-NITROBENZOATES, AND 2-CYCLOPROPYL-2-PROPYL PARA-NITROBENZOATES - EVIDENCE THAT C-13 CHEMICAL-SHIFTS OF CARBONIUM-IONS DO NOT CORRELATE WITH STABILITIES OF SOLVOLYTIC TRANSITION-STATES AND CORRESPONDING CATIONIC INTERMEDIATESB

被引：54

作者：

BROWN, HC ^{[1
]}

PETERS, EN ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1973年 / 95卷 / 07期

关键词：

D O I：

10.1021/ja00788a070

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2400 / 2402

页数：3

共 19 条

[1] Brown, 1972, BORANES ORGANIC CHEM
[2] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .26. RATES OF SOLVOLYSIS OF THE META-PHENYL AND PARA-PHENYL, META-METHYLTHIO AND PARA-METHYLTHIO AND META-TRIMETHYLSILYLPHENYLDIMETHYLCARBINYL AND PARA TRIMETHYLSILYLPHENYLDIMETHYLCARBINYL CHLORIDES - STERIC INHIBITION OF RESONANCE AS A FACTOR IN ELECTROPHILIC SUBSTITUENT CONSTANTS
BROWN, HC
OKAMOTO, Y
INUKAI, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) : 4964 - 4968
[3] RATES OF SOLVOLYSIS OF THE ALKYLPHENYLDIMETHYLCARBINYL CHLORIDES - EVIDENCE FOR THE IMPORTANCE OF CARBON-TO-CARBON HYPERCONJUGATIVE CONTRIBUTIONS IN ALKYL GROUPS
BROWN, HC
BRADY, JD
GRAYSON, M
BONNER, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (08) : 1897 - 1903
[4] COMPARISON OF RATES OF SOLVOLYSIS OF REPRESENTATIVE NORBORNYL + CYCLOPENTYL DERIVATIVES . CRITICAL EXAMINATION OF RATES AS BASIS FOR POSTULATED NONCLASSICAL STRUCTURE OF NORBORNYL CATIONS
BROWN, HC
REI, MH
CHLOUPEK, FJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (06) : 1247 - &
[5] STERIC INHIBITION OF INTERACTION OF A CYCLOPROPYL SUBSTITUENT WITH ELECTRON-DEFICIENT CENTER IN SOLVOLYSIS OF T-CUMYL DERIVATIVES
BROWN, HC
CLEVELAN.JD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (09) : 2051 - &
[6] EFFECT OF COPLANARITY ON RATES OF SOLVOLYSIS OF SEVERAL T-CUMYL CHLORIDE DERIVATIVES - ELECTROPHILIC SUBSTITUENT CONSTANTS FOR POLYCYCLIC AROMATICS
BROWN, HC
INUKAI, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (23) : 4825 - &
[7] CARBON-13 MAGNETIC RESONANCE .8. THEORY OF CARBON-13 CHEMICAL SHIFTS APPLIED TO SATURATED HYDROCARBONS
CHENEY, BV
GRANT, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) : 5319 - &
[8] CARBONIUM IONS .19. INTENSE CONJUGATION IN CYCLOPROPYL CARBONIUM IONS
DENO, NC
RICHEY, HG
LIU, JS
LINCOLN, DN
TURNER, JO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (20) : 4533 - &
[9] A CORRELATION OF REACTION RATES
HAMMOND, GS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (02) : 334 - 338
[10] INGOLD CK, 1970, STRUCTURE MECHANISM

← 1 2 →