HIGHLY SELECTIVE BROMINATION OF TETRAMESITYLPORPHYRIN - AN EASY ACCESS TO ROBUST METALLOPORPHYRINS, M-BR8TMP AND M-BR8TMPS - EXAMPLES OF APPLICATION IN CATALYTIC OXYGENATION AND OXIDATION REACTIONS

被引：132

作者：

HOFFMANN, P ^{[1
]}

LABAT, G ^{[1
]}

ROBERT, A ^{[1
]}

MEUNIER, B ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)88897-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The N-bromosuccinimide bromination of the zinc derivative of meso-tetramesitylporphyrin, Zn(TMP), in methanol at reflux in air, gives the corresponding (β-pyrrole)octabromo derivative, meso-tetramesityl-βoctabromoporphyrinatozinc, Zn(Br8TMP), in high yield (60-75%). Furthermore, the sulfonation by oleum of the metal-free ligand gives the persulfonated porphyrin, meso-tetrakis(3,5-disulfonatomesityl)-β-octabromoporphyrin, Br8TMPSH2 (70-75%). These robust manganese and iron derivatives are efficient catalysts in oxygen atom or electron transfer reactions. © 1990.

引用

页码：1991 / 1994

页数：4

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