OXIDATIONS OF AMINES .7. CHEMICAL AND ELECTROCHEMICAL CORRELATIONS

被引：63

作者：

HULL, LA

DAVIS, GT

ROSENBLA.DH

MANN, CK

机构：

[1] Research Laboratories, Edgewood Arsenal

[2] Department of Chemistry, Florida State University, Tallahassee

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 07期

关键词：

D O I：

10.1021/j100727a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Correlations of the logarithms of the rate constants for chlorine dioxide oxidations of aliphatic amines and of the amine polarographic peak potentials vs. the summations of σ* are reported. Also, correlations of the logarithms of the rate constants for chlorine dioxide oxidation of tertiary, secondary, and primary amines vs. amine pKa's are reported. The results suggest that electrochemical oxidation of amines and chemical oxidation by chlorine dioxide are similar.

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页码：2142 / &

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