HOMOPOLAR AND HETEROPOLAR BOND DISSOCIATION ENERGIES AND HEATS OF FORMATION OF RADICALS AND IONS IN GAS-PHASE .2. RELATIONSHIP BETWEEN STRUCTURE AND BOND DISSOCIATION IN ORGANIC-MOLECULES

被引：87
作者：
EGGER, KW [1 ]
COCKS, AT [1 ]
机构：
[1] MONSANTO RES SA,8050 ZURICH,SWITZERLAND
来源：
HELVETICA CHIMICA ACTA | 1973年 / 56卷 / 05期
关键词：
Bond dissociation - Bond dissociation energies - General aspects - Heats of formation - Heteropolar bonds - Organic molecules - Stabilization energy - Substituent effect;
D O I：
10.1002/hlca.19730560510
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preceeding paper presents a critical tabular compilation of 2-center homo- and heteropolar bond dissociation energies. This paper deals with some empirically derived general aspects of these data, particularly regarding relationships between structure and reactivity, i.e. substituent effects on bond dissociation energies. 'Extra' stabilization energies generated in electronically delocalized radicals or ions derived from these experimental data are also presented.
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页码：1537 / 1552
页数：16
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