INCORPORATION OF ANIONIC SPECIES IN ORGANOCLAY-MODIFIED ELECTRODES

被引：26

作者：

FALARAS, P

PETRIDIS, D

机构：

[1] National Center for Scientific Research Demokritos

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 337卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80540-K

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Clay-modified electrodes coated with cetyltrimethylammonium bromide present a particularly interesting chemical affinity towards anionic species. Incorporation and binding of electroactive anions such as Fe(CN)64-, Mo(CN)84- and Fe(C2O4)33- from aqueous solutions as dilute as 10(-7) M has been observed. Cyclic voltametry shows that the peak potentials of bound species shift in the negative direction compared with the corresponding values of free diffusing species.

引用

收藏

页码：229 / 239

页数：11

相关论文

共 17 条

[1] ELECTROCHEMICAL-BEHAVIOR OF CLAY MODIFIED ELECTRODES IN THE PRESENCE OF CATIONIC SURFACTANT [J].

BRAHIMI, B ;

LABBE, P ;

REVERDY, G .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 267 (1-2) :343-349

[2] PHOTOPROCESSES ON COLLOIDAL CLAY SYSTEMS .2. QUENCHING STUDIES AND THE EFFECT OF SURFACTANTS ON THE LUMINESCENT PROPERTIES OF PYRENE AND PYRENE DERIVATIVES ADSORBED ON CLAY COLLOIDS [J].

DELLAGUARDIA, RA ;

THOMAS, JK .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (18) :3550-3557

[3] CLAY MODIFIED ELECTRODES .3. ELECTROCHEMICAL AND ELECTRON-SPIN RESONANCE STUDIES OF MONTMORILLONITE LAYERS [J].

EGE, D ;

GHOSH, PK ;

WHITE, JR ;

EQUEY, JF ;

BARD, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (20) :5644-5652

[4] MONTMORILLONITE FACE SURFACE ASSOCIATED CR(BPY)3(3+) MONITORED ELECTROCHEMICALLY [J].

FITCH, A ;

LAVYFEDER, A ;

LEE, SA ;

KIRSH, MT .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (23) :6665-6670

[5] CLAY-MODIFIED ELECTRODES - A REVIEW [J].

FITCH, A .

CLAYS AND CLAY MINERALS, 1990, 38 (04) :391-400

[6] INSULATING PROPERTIES OF CLAY FILMS TOWARDS FE(CN)6(3-) AS AFFECTED BY ELECTROLYTE CONCENTRATION [J].

FITCH, A ;

FAUSTO, CL .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 257 (1-2) :299-303

[7] POTASSIUM OCTACYANOMOLYBDATE (IV) 2-HYDRATE - POTASSIUM MOLYBDOCYANIDE DIHYDRATE [J].

FURMAN, NH ;

MILLER, CO .

INORGANIC SYNTHESES, 1950, 3 :160-163

[8]

GREENLAND DJ, 1962, CLAYS CLAY MINER, V9, P499

[9] ELECTROCHEMISTRY AND PHOTOELECTROCHEMISTRY OF DYE-INCORPORATED CLAY-MODIFIED ELECTRODE [J].

KAMAT, PV .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 163 (1-2) :389-394

[10] OXOMETALATE-CLAY-MODIFIED ELECTRODES - EXAMPLE OF METATUNGSTATE INCORPORATED IN STEARYLTRIMETHYLAMMONIUM-MONTMORILLONITE LAYERS [J].

KEITA, B ;

DELLERO, N ;

NADJO, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 302 (1-2) :47-57