KINETICS AND MECHANISM OF THE ELECTROREDUCTION OF ANODIC LAYERS PRODUCED ON CADMIUM IN ALKALINE-SOLUTION CONTAINING SODIUM SULFIDE

被引：5

作者：

GASSA, LM ^{[1
]}

SAIDMAN, SB ^{[1
]}

VILCHE, JR ^{[1
]}

ARVIA, AJ ^{[1
]}

机构：

[1] NATL UNIV LA PLATA,FAC CIENCIAS EXACTAS,INST INVEST FISICOQUIM TEOR & APL,SUCURSAL 4,RA-1900 LA PLATA,ARGENTINA

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1991年 / 21卷 / 09期

关键词：

D O I：

10.1007/BF01402819

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The kinetics of the potentiostatic electroreduction of different anodic layers produced on cadmium in Na2S containing alkaline solutions has been studied at 25-degrees-C. Two types of anodic layer were used: (i) layers produced in the potential range of CdS and Cd(OH)2 stability, and (ii) layers predominantly composed of CdS. The electroreduction kinetics for both layers can be explained reasonably well throughout the nucleation and growth processes under diffusion control.

引用

页码：816 / 823

页数：8

共 28 条

[21] KINETICS AND MECHANISM OF H2O2 DECOMPOSITION CATALYZED BY CU-2+ IN ALKALINE-SOLUTION
LUO, Y
KUSTIN, K
EPSTEIN, IR
INORGANIC CHEMISTRY, 1988, 27 (14) : 2489 - 2496
[22] KINETICS AND MECHANISM OF THE OXIDATION OF HYPOPHOSPHITE WITH N-CHLOROTOLUENE-P-SULFONAMIDE (CHLORAMINE-T) CATALYZED BY OSMIUM(VIII) IN ALKALINE-SOLUTION
HUSSAIN, J
MISHRA, SK
SHARMA, PD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (01): : 89 - 92
[23] Mechanism and kinetics of anodic dissolution of aluminum and its alloys with zinc and rare-earths in a sodium polyvanadate solution
Kharina, GV
Kuznetsov, MV
Kochergin, VP
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 1998, 34 (05) : 482 - 485
[24] KINETICS AND MECHANISM OF THE ELECTROREDUCTION OF ANODIC LAYERS FORMED ON LEAD IN 5-M H2SO4 AT 25-DEGREES-C
VARELA, FE
GASSA, LM
VILCHE, JR
ELECTROCHIMICA ACTA, 1992, 37 (06) : 1119 - 1127
[25] STUDIES ON BROMITE .10. OXIDATIVE LACTONIZATION OF ALPHA,OMEGA-DIOLS WITH SODIUM BROMITE IN AN AQUEOUS ALKALINE-SOLUTION CONTAINING METAL-IONS
KAGEYAMA, T
YOSHIDA, Y
SUGIZAKI, T
NIPPON KAGAKU KAISHI, 1987, (09) : 1695 - 1698
[26] Mechanism of immersion deposition of Ni-P films on Si(100) in an aqueous alkaline solution containing sodium hypophosphite
Hsu, H. F.
Tsai, C. L.
Lee, C. W.
Wu, H. Y.
THIN SOLID FILMS, 2009, 517 (17) : 4786 - 4791
[27] KINETICS AND MECHANISM OF THE REDOX REACTION BETWEEN PT(IV) COMPLEX IONS AND SODIUM THIOSULFATE IN AQUEOUS SOLUTION. PART II: NEUTRAL AND ALKALINE SOLUTION
Paclawski, K.
Piwowonska, J.
ARCHIVES OF METALLURGY AND MATERIALS, 2014, 59 (04) : 1421 - 1426
[28] KINETICS AND MECHANISM OF SODIUM SULFIDE OXIDATION BY MOLECULAR-OXYGEN IN THE PRESENCE OF COPPER-CONTAINING ION-EXCHANGE RESIN KB-4
SHI, FC
ASTANINA, AA
RUDENKO, AP
VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1984, 25 (01): : 85 - 88

← 1 2 3 →