A STUDY OF THE ELECTRODEPOSITION OF MANGANESE FROM AQUEOUS CHLORIDE ELECTROLYTES

被引：34

作者：

GONSALVES, M

PLETCHER, D

机构：

[1] Department of Chemistry, The University, Southampton

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 285卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)87120-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cyclic voltammetry and potential step experiments at a vitreous carbon disc electrode and at a copper microdisc are used to investigate the electrodeposition of manganese metal from neutral aqueous ammonium chloride electrolytes. The importance of hydrogen evolution as the major competing reaction is confirmed and the parameters controlling the relative rates of proton and manganese(II) reduction are studied. The role of selenous acid as an additive to improve the current efficiency for manganese deposition is discussed. © 1990.

引用

页码：185 / 193

页数：9

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