Poly[aqua[mu-1,2-bis(pyridin-4-yl) ethene-kappa N-2:N'][mu-5-(diphenylphosphinoyl)isophthalato-kappa(3)O1,O-1' : O-3] nickel(II)]

被引：1

作者：

Zhang, Peng ^{[1
]}

Liu, Yu-Jie ^{[2
]}

Li, Kai-Hui ^{[1
]}

Yang, Guang-Rui ^{[1
]}

Mei, Chong-Zhen ^{[1
]}

机构：

[1] North China Univ Water Conservancy & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Henan, Peoples R China

[2] Nanyang Inst Technol, Sch Biochem & Chem Engn, Nanyang 473004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 13.1; mean σ(C-C) = 0.006 Å; R factor = 0.047; single-crystal X-ray study; T = 296 K; wR factor = 0.112;

D O I：

10.1107/S1600536812031108

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ni(C20H13O5P)(C12H10N2)(H2O)](n), the Ni-II cation is coordinated by three O atoms from two 5-(diphenylphosphinoyl) isophthalate anions, two N atoms from two 1,2-bis(pyridin-4-yl) ethene ligands and one water molecule in a distorted octahedral geometry. Both 1,2-bis( pyridin-4-yl) ethene and 5-(diphenylphosphinoyl) isophthalate bridge the Ni-II cations to form polymeric layers parallel to (001). In the crystal, O-H ... O hydrogen bonding links layers into a three-dimensional supramolecular structure.

引用

页码：M1058 / +

页数：12

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