ONE-ELECTRON REDUCTION OF 1,5-DIHYDROFLAVINS IN AQUEOUS-SOLUTION - A PULSE-RADIOLYSIS STUDY

被引：6
作者：
HEELIS, PF
PARSONS, BJ
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 07期
关键词：
D O I：
10.1039/c39940000793
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-electron reduction of 1,5-dihydroflavins with e(aq)- yields a three-electron reduced flavin species (FIH2.-), which protonates with an associated pK(a) value of 6.1, whereas the reaction of 1,5-dihydroflavins with CO2.- yields a similar, but not identical flavin species, which may be an adduct radical.
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页码：793 / 794
页数：2
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