EPR-SPECTRA OF 3,5-DISUBSTITUTED BENZYL RADICALS

被引：12
作者：
JACKSON, RA
MOOSAVI, R
机构：
[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 06期
关键词：
D O I：
10.1039/p29920000885
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A careful determination has been made of the EPR coupling constants Of a series of seven 3,5-disubstituted benzyl radicals to assess the influence of meta substituents on delocalization of the unpaired electron. a(CH2) depends on sigma(m) (major component) and sigma(H). (minor component).
引用
收藏
页码：885 / 888
页数：4
相关论文
共 50 条
[41]   CYCLIACYLATION STUDIES ON 3,5-DISUBSTITUTED PHENYLALKANOIC ACIDS [J].
NEWMAN, MS ;
LANDERS, JO .
JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (15) :2556-2559
[42]   SYNTHESIS OF 3,5-DISUBSTITUTED PYRIDINES AS ANTIMICROBIAL AGENTS [J].
ATTIA, A ;
ABOGHALIA, MH ;
ELSALAM, OIA .
PHARMAZIE, 1995, 50 (07) :455-459
[43]   SYNTHESES OF 3,5-DISUBSTITUTED 2-OXOPIPERAZINES [J].
MASUZAWA, K ;
UCHIDA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1967, 40 (11) :2691-+
[44]   SOME 3,5-DISUBSTITUTED BENZOTRICHLORIDES AS POSSIBLE INSECTICIDES [J].
SMITH, WT ;
PATTERSON, JM ;
CHEN, HH .
JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (11) :4713-&
[45]   PHASE REVERSALS IN EPR-SPECTRA [J].
EDGAR, A .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1975, 8 (03) :179-180
[46]   EPR-SPECTRA, STRUCTURE AND REACTIVITY OF AROMATIC CATION-RADICALS IN SUPER ACIDS [J].
RUDENKO, AP .
ZHURNAL ORGANICHESKOI KHIMII, 1994, 30 (12) :1847-1881
[47]   Vibrational structure of EPR-spectra? [J].
Ortega, S. ;
Handel, L. D. ;
Passeggi, M. C. ;
Buch, T. .
CHEMICAL PHYSICS LETTERS, 1969, 3 (01) :35-36
[48]   EPR-SPECTRA OF HYDRAZYL AND SOME 1-SUBSTITUTED HYDRAZYL RADICALS IN SOLUTION [J].
MALATESTA, V ;
LINDSAY, D ;
HORSWILL, EC ;
INGOLD, KU .
CANADIAN JOURNAL OF CHEMISTRY, 1974, 52 (05) :864-866
[49]   EPR-SPECTRA OF ERYTHROCUPREIN IN SOLUTION [J].
SYMONYAN, MA ;
NALBANDYAN, RM .
STUDIA BIOPHYSICA, 1976, 54 (02) :99-103
[50]   A CONSISTENT DESCRIPTION OF EPR-SPECTRA [J].
ZHONG, YC ;
PILBROW, JR .
JOURNAL OF MAGNETIC RESONANCE, 1991, 93 (03) :447-457
12345