EPR-SPECTRA OF 3,5-DISUBSTITUTED BENZYL RADICALS

被引：12
作者：
JACKSON, RA
MOOSAVI, R
机构：
[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 06期
关键词：
D O I：
10.1039/p29920000885
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A careful determination has been made of the EPR coupling constants Of a series of seven 3,5-disubstituted benzyl radicals to assess the influence of meta substituents on delocalization of the unpaired electron. a(CH2) depends on sigma(m) (major component) and sigma(H). (minor component).
引用
收藏
页码：885 / 888
页数：4
相关论文
共 50 条
[21]   A synthetic entry to 3,5-disubstituted pyridines [J].
Bennasar, ML ;
Zulaica, E ;
Roca, T ;
Alonso, Y ;
Monerris, M .
TETRAHEDRON LETTERS, 2003, 44 (25) :4711-4714
[22]   OBSERVATION OF BROAD EPR-SPECTRA OF TRANSIENT FREE-RADICALS BY FT-EPR [J].
OHBA, Y ;
OKABE, N ;
SATOH, R ;
YAMAMOTO, K ;
YAMAUCHI, S ;
IWAIZUMI, M .
APPLIED MAGNETIC RESONANCE, 1994, 6 (1-2) :51-66
[23]   PROTON AND CARBON NMR-SPECTRA AND STEREOCHEMICAL ASSIGNMENTS FOR 3,5-DISUBSTITUTED NORTRICYCLENES [J].
CHIZHOV, AO ;
ZEFIROV, NS ;
ZYK, NV ;
MORRILL, TC .
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (26) :5647-5655
[24]   INTEGRATION OF EPR-SPECTRA [J].
SCHICK, A ;
RAGER, H .
APPLIED MAGNETIC RESONANCE, 1993, 4 (03) :367-375
[25]   EPR-SPECTRA OF POLYTETRAFLUOROETHYLENE TREATED WITH SOLUTIONS OF NAPHTHALENE ANION-RADICALS [J].
SOLODOVNIKOV, SP .
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1977, 19 (09) :696-698
[26]   EPR-SPECTRA AND ELECTRONIC-STRUCTURE OF BETA-CARBONYL RADICALS [J].
PRATT, DW ;
CAMAIONI, DM ;
WALTER, HF .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, :71-&
[27]   EPR-SPECTRA OF FREE-RADICALS OF BETA-PHOSPHORYLATED OXIMES [J].
BARLEV, AA ;
ILYASOV, AV ;
MUKHTAROV, AS ;
SHERMERGORN, IM ;
VAFINA, NM .
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (05) :1033-1035
[28]   EPR-SPECTRA OF DMPO SPIN ADDUCTS OF SUPEROXIDE AND HYDROXYL RADICALS IN PYRIDINE [J].
RESZKA, K ;
BILSKI, P ;
CHIGNELL, CF .
FREE RADICAL RESEARCH COMMUNICATIONS, 1992, 17 (06) :377-385
[29]   EPR-SPECTRA OF FREE-RADICALS FROM IMIDOYL CHLORIDE DERIVATIVES [J].
TUMANSKII, BL ;
PETROV, VA ;
GRINEVSKAYA, VK ;
SOLODOVNIKOV, SP ;
BUBNOV, NN .
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (12) :2585-2586
[30]   Synthesis of N-benzyl 3,5-disubstituted piperidines via double Michael addition strategy [J].
Lee, MJ ;
Lee, KY ;
Kim, JN .
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (03) :477-480
12345