EPR-SPECTRA OF 3,5-DISUBSTITUTED BENZYL RADICALS

被引：12
作者：
JACKSON, RA
MOOSAVI, R
机构：
[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 06期
关键词：
D O I：
10.1039/p29920000885
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A careful determination has been made of the EPR coupling constants Of a series of seven 3,5-disubstituted benzyl radicals to assess the influence of meta substituents on delocalization of the unpaired electron. a(CH2) depends on sigma(m) (major component) and sigma(H). (minor component).
引用
收藏
页码：885 / 888
页数：4
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