PHOSPHONITRILIC COMPOUNDS .8. REACTION OF O-AMINOPHENOL WITH PHOSPHAZENES

被引：37
作者：
ALLCOCK, HR
KUGEL, RL
机构：
[1] Department of Chemistry, Pennsylvania State University, University Park
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 20期
关键词：
D O I：
10.1021/ja01048a009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
o-Aminophenol reacts with a number of halo- and organophosphazenes in boiling xylene to yield bis-(o-phenyleneoxyamino)-2-aminophenoxyphosphorane (III) and ammonium halide or ammonia. This ring cleavage reaction occurs with (NPCI2)3, (NPCI2)4, (NPCI2)15.000, (NPBr2)3, (NPF2)3, and with certain organocyclotriphospha-zenes which contain a five-membered cyclic side unit attached to phosphorus. No reaction was observed with [NP-(OC6H5)2]3, [NP(OC6H4NO2)2]3, [NP(NHC6H5)2]3, or [NP(O2C12H8)]3. The structural proof for III is described and the complex reaction mechanism is discussed. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码：5452 / &
相关论文
共 26 条
[1]   PHOSPHONITRILIC COMPOUNDS .7. HIGH MOLECULAR WEIGHT POLY(DIAMINOPHOSPHAZENES) [J].
ALLCOCK, HR ;
KUGEL, RL .
INORGANIC CHEMISTRY, 1966, 5 (10) :1716-&
[2]   PHOSPHONITRILIC COMPOUNDS .6. HIGH MOLECULAR WEIGHT POLY(ALKOXY- AND ARYLOXPHOSPHAZENES) [J].
ALLCOCK, HR ;
KUGEL, RL ;
VALAN, KJ .
INORGANIC CHEMISTRY, 1966, 5 (10) :1709-&
[3]   PHOSPHONITRILIC COMPOUNDS .I. MECHANISM OF PHOSPHONITRILIC CHLORIDE POLYMERIZATION CAPACITANCE CONDUCTANCE + ELECTRON-SPIN RESONANCE STUDIES [J].
ALLCOCK, HR ;
BEST, RJ .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1964, 42 (02) :447-&
[4]   DEGRADATION OF HALOGENOPHOSPHAZENES TO A NEW PHOSPHORANE SYSTEM [J].
ALLCOCK, HR ;
KUGEL, RL .
CHEMICAL COMMUNICATIONS, 1968, (24) :1606-&
[5]   PHOSPHONITRILIC COMPOUNDS .2. REACTIONS OF PHOSPHONITRILIC CHLORIDES WITH CATECHOL + TRIETHYLAMINE [J].
ALLCOCK, HR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (13) :2591-&
[6]   PHOSPHONITRILIC COMPOUNDS .V. CYCLIZED PRODUCTS FROM REACTIONS OF HEXACHLOROCYCLOTRIPHOSPHAZENE (PHOSPHONITRILIC CHLORIDE TRIMER) WITH AROMATIC DIHYDROXY DITHIOL AND DIAMINO COMPOUNDS [J].
ALLCOCK, HR ;
KUGEL, RL .
INORGANIC CHEMISTRY, 1966, 5 (06) :1016-&
[7]  
ALLCOCK HR, 1967, HETEROATOM RING SYST, pCH7
[8]  
ALLCOCK HR, UNPUBLISHED WORK
[9]   ZUR KENNTNIS DER PHOSPHORNITRILCHLORIDE .2. REAKTIONEN VON NUCLEOPHILEN REAGENTIEN MIT TRIMEREM PHOSPHORNITRILCHLORID [J].
BECKEGOEHRING, M ;
JOHN, K ;
FLUCK, E .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1959, 302 (1-2) :103-120
[10]   UBER PHOSPHORNITRIL-VERBINDUNGEN .4. DIE STRUKTUR UND UBER AMIDE DES TRIMEREN [J].
BODE, H ;
BUTOW, K ;
LIENAU, G .
CHEMISCHE BERICHTE-RECUEIL, 1948, 81 (06) :547-552
123