AN INVESTIGATION OF MODIFIED AGI SOLID ELECTROLYTES CONTAINING THE HOMOPIPERAZINIUM CATION .2. ELECTROCHEMICAL-BEHAVIOR IN THE N, N, N', N'-TETRAMETHYLHOMOPIPERAZINIUM DIIODIDE-SILVER IODIDE SYSTEM AND APPLICATION TO SOLID-STATE BATTERIES

被引：0
|
作者：
ROSENBERG, JJ
BOUZOU, M
CERCLIER, O
ESTIENNE, J
机构：
[1] UNIV PROVENCE,CTR ST JEROME,CHIM ORGAN STRUCT LAB,F-13397 MARSEILLE,FRANCE
[2] UNIV AIX MARSEILLE 1,CTR DIFFRACTOMETRIE,F-13331 MARSEILLE 3,FRANCE
来源：
ELECTROCHIMICA ACTA | 1993年 / 38卷 / 04期
关键词：
SILVER IODIDE; SILVER SOLID ELECTROLYTE; HOMOPIPERAZINIUM DIIODIDE; REDOX STABILITY RANGE; IONIC CONDUCTION; TUBANDT METHOD; HEBB-WAGNER METHOD; ELECTRONIC CONDUCTION; TRANSPORT NUMBER; GENERATORS POLARIZATIONS; SCANNING ELECTRONIC MICROSCOPE (SEM); OPTICAL MICROSCOPE (OM);
D O I：
10.1016/0013-4686(93)85014-P
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Electrochemical behavior of the best conductive composition in the system N, N, N', N'-tetramethylhomopiperazinium diiodide-silver iodide is studied. It presents a transport number of silver ions, within the limit of experimental error, of unity. Its electronic conductivity is 10(-9) (ohm cm)-1. Its redox stability range is comprised between 0 and 690 mV. Electrodes particles diameter, morphology and surface area are studied with a particle analyser, SEM and OM photos. This electrolyte is tried in an all-solid generator. Cathodic polarizations are predominant when the microgenerator is discharged.
引用
收藏
页码：571 / 575
页数：5
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