A RUTHENIUM DIHYDROGEN COMPLEX AS INTERMEDIATE IN THE SYNTHESIS OF [RUH(CO)2(MECO2)(PNBU3)2] FROM [RU(H)2(CO)2(PNBU3)2]

被引：7
作者：
FREDIANI, P
SALVINI, A
BIANCHI, M
PIACENTI, F
机构：
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)83258-W
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The acetatohydride, [RUH(CO)2(MeCO2)(PnBU3)2], a likely intermediate in the transformation of [Ru(CO)2(MeCO2)2(PnBU3)2] into [Ru(H)2(CO)2(PnBU3)2] by reaction with dihydrogen, has been synthesized by reaction of [Ru(H)2(CO)2(PnBu3)2] with acetic acid, and then spectroscopically characterized. Evidence has been obtained of the involvement of the dihydrogen intermediate [Ru(H2)(CO)2-(P(n)Bu)2].
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页码：C17 / C19
页数：3
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