BIS(DIETHYLENETRIAMINE-N'-ACETATO)-DI-MU-HYDROXO-DICOBALT(III) PERCHLORATE

被引：5

作者：

CHEN, MQ ^{[1
]}

LIU, J ^{[1
]}

机构：

[1] NANJING UNIV,INST COORDINAT CHEM,COORDINAT CHEM STATE KEY LAB,NANJING 210008,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194013387

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex cation of the title compound, bis[bis(2-aminoethyl)aminoacetato] -di-mu-hydroxo-dicobalt(III), [Co-2(C6H14N3O2)(2)(mu-OH)(2)](ClO4)(2), has a dinuclear structure, with two OH bridges, Each Co atom is octahedrally surrounded by a bis(2-aminoethyl)aminoacetate tripodal structure and two OH groups. In the crystal structure, intermolecular O-H ... O hydrogen bonds form infinite chains of molecules, which significantly stabilizes the dinuclear structure; the Co ... Co distance is 2.863(1) Angstrom.

引用

页码：1080 / 1082

页数：3