catena-Poly[[[diaqua(1,10-phenanthroline-kappa N-2,N ')cobalt(II)]-mu-4-hydroxy-3-sulfonatobenzoato-kappa O-2(3):O-1] sesquihydrate]

被引：1

作者：

Fang, Xiang-Qian ^{[1
]}

Gao, Shan ^{[1
]}

Ng, Seik Weng ^{[2
,3
]}

机构：

[1] Heilongjiang Univ, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Heilongjiang, Peoples R China

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[3] King Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah, Saudi Arabia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812018752

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The 1,10-phenanthroline-chelated Co-II atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)(2)]center dot 1.5H2O}(n), is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.

引用

页码：M721 / +

页数：8

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