COMPLETE H-1 AND C-13 NMR SPECTRAL ASSIGNMENT OF PENTACYCLO [6.4.0.0(2,6).0(5,9).0(4,12)]DODECANE DERIVATIVES AND STRUCTURE ELUCIDATION OF PENTACYCLO [6.4.0.0(2,6).0(3,11).0(5,9)]DODECANE

被引：18

作者：

MARTINS, FJC

COETZEE, GH

FOURIE, L

VENTER, HJ

VILJOEN, AM

WESSELS, PL

机构：

[1] Department of Chemistry, Potchefstroom University for C.H.E, Potchefstroom

[2] Department of Chemistry, University of Pretoria, Pretoria

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 06期

关键词：

PENTACYCLODODECANE MOLECULES; H-1; NMR; C-13; HOMO NUCLEAR AND HETERONUCLEAR SPI EXPERIMENTS; NOE DIFFERENCE SPECTRA;

D O I：

10.1002/mrc.1260310611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of pentacyclo[6,4.0.0(2.6).0(5.9).0(4,12)]dodecan-2-ol with concentrated sulphuric acid produced the rearranged hydrocarbon pentacyclo[6.4.0.0(2,6).0(3,11).0(5,9)]dodecane as the main product. High-field H-1 and C-13 NMR techniques were used in the structure elucidation and assignment of the different NMR resonances of these two and related compounds.

引用

页码：578 / 584

页数：7

共 18 条

[1]

ALLINGER N. L., 1976, ADV PHYS ORG CHEM, V13, P1

[2] 2-DIMENSIONAL SPECTROSCOPY - APPLICATION TO NUCLEAR MAGNETIC-RESONANCE [J].