[2,3-DI(2-PYRIDYL)PYRAZINE-N-1,N-2']BIS-(TRIPHENYLPHOSPHINE)COPPER(I) NITRATE ETHANOL SOLVATE

被引：10

作者：

BROOKS, KT

FINNEN, DC

KIRCHHOFF, JR

PINKERTON, AA

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194007080

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The copper(I) complex [CU(C14H10N4)(C18H15P)(2)]- (NO3).C2H6O, has been synthesized its structure determined. The coordination geometry about the Cu atom is distorted tetrahedral with bidentate chelation to dpp, where dpp is 2,3-di(2-pyridyl)pyrazine, and monodentate coordination to two triphenylphosphine ligands.

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页码：1696 / 1699

页数：4

相关论文

共 13 条

[1] EXCITED-STATE ABSORPTION-SPECTROSCOPY AND SPECTROELECTROCHEMISTRY OF TETRAKIS(2,2'-BIPYRIDINE)(MU-2,3-BIS(2-PYRIDYL)PYRAZINE)DIRUTHENIUM(II) AND ITS MONONUCLEAR COUNTERPART - A COMPARATIVE-STUDY [J].

BERGER, RM .

INORGANIC CHEMISTRY, 1990, 29 (10) :1920-1924

[2]

BLESSING RH, 1974, J APPL CRYSTALLOGR, V7, P488

[3] SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF THE DIMER TETRAKIS(2,2'-BIPYRIDINE)(MU-2,3-BIS(2-PYRIDYL)PYRAZINE)DIRUTHENIUM(II) AND ITS MONOMERIC ANALOG [J].

BRAUNSTEIN, CH ;

BAKER, AD ;

STREKAS, TC ;

GAFNEY, HD .

INORGANIC CHEMISTRY, 1984, 23 (07) :857-864

[4] LEWIS-BASE ADDUCTS OF GROUP-1B METAL(I) COMPOUNDS .13. CRYSTAL-STRUCTURE DETERMINATIONS OF TETRAKIS(TRIPHENYLPHOSPHINE)-COPPER(I) AND TETRAKIS(TRIPHENYLPHOSPHINE)-SILVER(I) PERCHLORATES, BIS(PYRIDINE)BIS(TRIPHENYL-PHOSPHINE)COPPER(I) PERCHLORATE, (2,2'-BIPYRIDYL)BIS(TRIPHENYL-PHOSPHINE)COPPER(I) PERCHLORATE, AND TETRAHYDROBORATOBIS-(TRIPHENYLPHOSPHINE)COPPER(I) PYRIDINE (1/0.5)E [J].

ENGELHARDT, LM ;

PAKAWATCHAI, C ;

WHITE, AH ;

HEALY, PC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (01) :125-133

[5]

FAIR CK, 1990, MOLEN INTERACTIVE IN

[6] STRUCTURE OF 2,3-BIS(2-PYRIDYL)PYRAZINE [J].

HUANG, NT ;

PENNINGTON, WT ;

PETERSEN, JD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :2011-2012

[7]

Johnson C.K., 1976, ORNL5138 OAK RIDG NA

[8] STERIC EFFECTS AND THE BEHAVIOR OF CU(NN)(PPH3)2+ SYSTEMS IN FLUID SOLUTION - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(DMP)(PPH3)2]NO3 AND [CU(PHEN)(PPH3)2]NO3.11/2ETOH [J].

KIRCHHOFF, JR ;

MCMILLIN, DR ;

ROBINSON, WR ;

POWELL, DR ;

MCKENZIE, AT ;

CHEN, S .

INORGANIC CHEMISTRY, 1985, 24 (23) :3928-3933

[9]

LEE YF, 1994, UNPUB INORG CHEM

[10] SYNTHESIS AND STRUCTURE OF INFINITE-CHAIN COPPER(II) POLYMER SYSTEMS [J].

MORGAN, LW ;

GOODWIN, KV ;

PENNINGTON, WT ;

PETERSEN, JD .

INORGANIC CHEMISTRY, 1992, 31 (06) :1103-1106