THEORY OF CYCLIC VOLTAMMETRY FOR A DIMERIZATION REACTION INITIATED ELECTROCHEMICALLY

被引：281

作者：

OLMSTEAD, ML

HAMILTON, RG

NICHOLSON, RS

机构：

[1] Chemistry Department, Michigan State University, East Lansing

来源：

ANALYTICAL CHEMISTRY | 1969年 / 41卷 / 02期

关键词：

D O I：

10.1021/ac60271a032

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Theory of cyclic voltammetry is presented for an electrochemically initiated homogeneous dimerization reaction. The mathematical approach treats the linear partial differential equation by transformation to integral form and the nonlinear differential equation by finite difference. This approach should be of general interest, and therefore it is described in adequate detail. Results of the calculations both for planar and spherical electrodes are presented as diagnostic criteria analogous to those developed previously for a first-order reaction initiated electrolytically. Finally, a method is presented by which the dimerization rate constant can be evaluated from a single cyclic polarogram. © 1969, American Chemical Society. All rights reserved.

引用

页码：260 / +

页数：1

共 16 条

[1]

APOSTOL TM, 1957, MATHEMATICAL ANALYSI, P93

[2] GENERALIZED NUMERICAL METHOD FOR STATIONARY ELECTRODE POLAROGRAPHY - APPLICATION TO REACTIONS INVOLVING SECOND-ORDER HOMOGENEOUS CHEMICAL COMPLICATIONS [J].