2,4,6,8-Tetrakis(4-chlorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one O-benzyloxime acetone monosolvate

被引:4
作者
Park, Dong Ho [1 ]
Ramkumar, V. [2 ]
Parthiban, P. [1 ]
机构
[1] Inje Univ, Dept Biomed Chem, Gimhae 621749, Gyeongnam, South Korea
[2] IIT Madras, Dept Chem, Madras 600036, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
D O I
10.1107/S1600536812016509
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C38H31Cl4N3O center dot C3H6O, the 3,7-diazabicycle exists in a chair-boat conformation. The 4-chlorophenyl groups attached to the chair form are equatorially oriented at an angle of 18.15 (3)degrees with respect to each other, whereas the 4-chlorophenyl groups attached to the boat form are oriented at an angle of 32.64 (3)degrees. In the crystal, molecules are linked by N-H center dot center dot center dot pi and C-H center dot center dot center dot O interactions.
引用
收藏
页码:O1481 / +
页数:11
相关论文
共 12 条
[1]   COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, C ;
GUAGLIARDI, A .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350
[2]  
Asakawa Y., 1995, PROGR CHEM ORGANIC N
[3]  
Bruker, 2004, APEX2 SAINT PLUS SAD
[4]   GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].
CREMER, D ;
POPLE, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358
[5]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
[6]   CHEMISTRY OF 3-AZABICYCLO[3.3.1]NONANES [J].
JEYARAMAN, R ;
AVILA, S .
CHEMICAL REVIEWS, 1981, 81 (02) :149-174
[7]   PUCK-2, AN IMPROVED VERSION OF THE CREMER-POPLE PUCKERING PROGRAM [J].
LUGER, P ;
BULOW, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1983, 16 (AUG) :431-432
[9]   1H and 13C NMR spectral assignments of some novel 2,4,6,8-tetraaryl-3,7-diazabicyclo[3.3.1]nonan-9-one derivatives [J].
Parthiban, Paramasivam ;
Ramachandran, Rajamanickam ;
Aridoss, Gopalakrishnan ;
Kabilan, Senthamaraikannan .
MAGNETIC RESONANCE IN CHEMISTRY, 2008, 46 (08) :780-785
[10]   Stereocontrolled facile synthesis and antimicrobial activity of oximes and oxime ethers of diversely substituted bispidines [J].
Parthiban, Paramasivam ;
Kabilan, Senthamaraikannan ;
Ramkumar, Venkatachalam ;
Jeong, Yeon Tae .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2010, 20 (22) :6452-6458