Crystal structure of 1,1 '-bis(2-methoxycarbonyl-2-methylpropyl)ferrocene

被引：0

作者：

Guo, Yan-Feng ^{[1
]}

Wang, Jian-Jun ^{[1
]}

Xu, Wei-Juan ^{[1
]}

Sun, Dong-Hao ^{[1
]}

Gao, Qiang ^{[2
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China

[2] Jiangnan Univ, Coll Text & Clothing, Key Lab Ecotext, Minist Educ, Wuxi 214122, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; inversion symmetry; disubstituted ferrocene; ester;

D O I：

10.1107/S2056989015020642

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Fe atom in the title ferrocene derivative, [Fe(C11H15O2)(2)], is situated on an inversion centre. As a result of the point-group symmetry 1 of the molecule, the ferrocene moiety adopts a staggered conformation. The average Fe-C(Cp) bond length (Cp is cyclopentadienyl) is 2.045 (4) angstrom, in agreement with that of other disubstituted ferrocenes. The Fe-C bond length involving the substituted C atom is slightly longer [2.0521 (17) angstrom] than the remaining Fe-C bond lengths caused by the inductive effect of the methylene group on the Cp ring. Apart from van der Waals forces, no significant intermolecular interactions are observed in the crystal packing.

引用

页码：M213 / U137

页数：8

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