METAL-COMPLEXES IN INORGANIC MATRICES .13. NICKEL-COMPLEXES WITH LYSINATE-SUBSTITUTED TITANIUM ALKOXIDES AS LIGANDS - X-RAY STRUCTURE-ANALYSIS OF [(ETO)(3)TI(GLYCINATE)](2)

被引：44

作者：

SCHUBERT, U ^{[1
]}

TEWINKEL, S ^{[1
]}

MOLLER, F ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,D-97074 WURZBURG,GERMANY

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 04期

关键词：

D O I：

10.1021/ic00108a037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Ti(OEt)(4) with amino acids results in alkoxide carboxylate derivatives, in which the amino carboxylate group chelates the Ti(OEt)(3) moiety via one oxygen atom and the NH2 group. An X-ray structure analysis of the glycine derivative showed the compound to be dimeric, with the two Ti atoms bridged by two OEt group. When lysine is used, only the alpha-amino group coordinates to the metal while the terminal amino group is dangling and can be used to coordinate metal ions.

引用

页码：995 / 997

页数：3

共 11 条

[1]

BRADLEY DC, 1978, METAL ALKOXIDES, P120

[2] METAL-COMPLEXES IN INORGANIC MATRICES .10. PREPARATION OF PHOSPHANYL SPACER-SUBSTITUTED METAL ALKOXIDES (RO)3E-X-PPH2 (E = TI, ZR - X = SPACER) [J].

BUHLER, H ;

SCHUBERT, U .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (02) :405-406

[3] 3-CHLOROPROPYLTRIALKOXYSILANES - KEY INTERMEDIATES FOR THE COMMERCIAL PRODUCTION OF ORGANOFUNCTIONALIZED SILANES AND POLYSILOXANES [J].

DESCHLER, U ;

KLEINSCHMIT, P ;

PANSTER, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1986, 25 (03) :236-252

[4]

Deschler U., 1986, ANGEW CHEM, V98, P237

[5]

Laurie S.H., 1987, COMPREHENSIVE COORDI, V2, P739

[6] SOL-GEL CHEMISTRY OF TRANSITION-METAL OXIDES [J].

LIVAGE, J ;

HENRY, M ;

SANCHEZ, C .

PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (04) :259-341

[7]

Mehrotra R. C., 1983, METAL CARBOXYLATES

[8]

SCHUBERT U, 1994, NEW J CHEM, V18, P1049

[9] METAL-COMPLEXES IN INORGANIC MATRICES .8. CHROMIUM TRICARBONYL COMPLEXES OF BENZOYLACETONATE-SUBSTITUTED TITANIUM-ALKOXIDE, ZIRCONIUM-ALKOXIDE, AND ALUMINUM-ALKOXIDES [J].

SCHUBERT, U ;

BUHLER, H ;

HIRLE, B .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (05) :999-1003

[10]

SCHUBERT U, 1994, MATER RES SOC SYMP P, V351, P141, DOI 10.1557/PROC-351-141

← 1 2 →