DIGITAL-SIMULATION OF CHARGE-TRANSFER TO AN ULTRAMICRODISC INTERFACE

被引：46

作者：

TAYLOR, G

GIRAULT, HH

MCALEER, J

机构：

[1] DEPT CHEM,KINGS BLDGS,W MAINS RD,EDINBURGH EH9 3JJ,SCOTLAND

[2] MEDISENSE UK INC,ABINGDON OX14 1DY,OXON,ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 293卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)80050-G

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel space-grid expansion in two dimensions coupled with an ADI method allowing implicit determination of boundary concentrations is presented. These yield a fast and accurate algorithm applied to cyclic voltammetry and chronoamperometry for reversible, quasi-reversible and irreversible charge transfer at ultramicrodisc interfaces. The effects of the kinetic parameters k, Λ, α on current-potential-time response curves are studied. © 1990.

引用

页码：19 / 44

页数：26

共 28 条

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