THERMAL-DEGRADATION STUDIES OF TEREPHTHALATE POLYESTERS .2. POLY(ETHER-ESTERS)

被引：35

作者：

BOUNEKHEL, M ^{[1
]}

MCNEILL, IC ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,LANARK,SCOTLAND

来源：

POLYMER DEGRADATION AND STABILITY | 1995年 / 49卷 / 03期

关键词：

D O I：

10.1016/0141-3910(95)00097-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(ether-esters) based on terephthaloyl chloride and poly(ethylene glycol) oligomers, of molecular weight 200 and 1000, respectively, have been prepared and their stability has been investigated by similar techniques to those used in the examination of poly(alkylene terephthalates) in Part 1. When subjected to programmed rise in temperature, both polymers showed one stage of decomposition and evolved similar types of degradation product, although with different onset temperatures and different relative amounts of products. A general mechanism for the decomposition of these poly(ether-esters) is proposed.

引用

页码：347 / 352

页数：6

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